The handful of popular DEs [0] are going to be much more polished and functional for like 99% of tasks, and nonexistent [1] for the other 1%. The OS settings are conveniently located in a sensibly organized system settings manager and it works great. Then you need to mount a network drive (temporarily or permanently) and simply cannot do so in a GUI. If you're comfortable dealing with that small handful of outlier tasks (and if you're here, you can probably manage), then they're all already there.
[0] I use KDE, but it's essentially true of all of them
[0] I use KDE, but it's essentially true of all of them
[1] that is, they require the command line