Methane has 28% more energy per kg than kerosene and also produces slightly less CO2 (2.75kg CO2/kg burned vs 3.00 for kerosene) when burned [1]. SpaceX uses a 78:22 LOX to CH4 ratio, so for 34M kg of fuel burned, 20.57M kg of CO2 are produced (34×0.22×2.75).
[1] https://www.engineeringtoolbox.com/co2-emission-fuels-d_1085... [2] https://x.com/elonmusk/status/1298426245991063554?lang=en