My impression of nix package maintainers is that they are providing a useful interface so that software can be composed easily. Most of them are not making any kind of assertion about the contents of the package. Expecting to use their signatures for anything meaningful strikes me as a bit like expecting product support from a delivery driver.
You don't need to trust it wasn't packaged maliciously, nix does reproducible builds so you can just look at the derivation and build it yourself if you don't feel like relying on the binary cache.
As for whether the underlying contents are malicious, that's between you and the developer. If other distributions have have lead you to believe otherwise, then I think they have misled you.
The only exception I can think of is Tails, and they don't exactly have the breadth that Nix does.
You don't need to trust it wasn't packaged maliciously, nix does reproducible builds so you can just look at the derivation and build it yourself if you don't feel like relying on the binary cache.
As for whether the underlying contents are malicious, that's between you and the developer. If other distributions have have lead you to believe otherwise, then I think they have misled you.
The only exception I can think of is Tails, and they don't exactly have the breadth that Nix does.