Here 100 is how many seconds you will have to keep the cursor on the edge of the screen before the Dock appears. You could set it to 3 or 5 should you need the Dock sometimes but don't want to trigger it by accident.
[Edit: Autohide can be toggled on/off also with ⌥+⌘+D. You can use the combination to show/hide the Dock, paired with a high autohide delay.]
[Edit: Autohide can be toggled on/off also with ⌥+⌘+D. You can use the combination to show/hide the Dock, paired with a high autohide delay.]