Comment
Comment by stonesweep
Each DE can have slightly different paths, but in general find the file mimeapps.list. It's typically looked for in the traditional manner of /etc/, /usr/share/ and /usr/local/share/ and $HOME to find global, local and personal configurations. In your $HOME it's usually something like this:
In here you find the MIME type pointing at a .desktop file (app launcher), it's a matter of changing that. Mine for example related to using Firefox:
Find the .desktop file you want to launch and just update that bad boy. Most DEs have a GUI tool to manage this for you without having to resort to manual editing...