SAT is best when there is one true logical answer. ANN are best when you want "best advice".
A good guide (in my experience) -- with SAT while the answer is hard to find it's easy to check (like a Sudoku, or building a timetable with no clashes), while ANN give answers where verifying the answer isn't easy to perform computstionally (if I give you a translation of a text into Latin, verifying it is about as hard as just making a new one from scratch)
A good guide (in my experience) -- with SAT while the answer is hard to find it's easy to check (like a Sudoku, or building a timetable with no clashes), while ANN give answers where verifying the answer isn't easy to perform computstionally (if I give you a translation of a text into Latin, verifying it is about as hard as just making a new one from scratch)