Comment by braised_babbage

This is, strictly speaking, not true. Talking about an "orthonormal" basis implies that you have in mind some Hilbert space; but in any such instance there will be interesting functions that are not in this Hilbert space. So consider for example the standard space L^2(R) of square-integrable functions on the real line. This does not contain the function f(x) = 1, as a really dumb example.