I have been getting native IPv6 from my ISP for nearly six years now. It is not quite as cool as it could be, because I get assigned a new prefix every 24 hours, but still, IPv6 is there, and it "just works".
When I connect to machines on my home network in any way involving avahi/zeroconf, the machines talk to each other via IPv6 by default.
At work, it's a different story. I have drifted from a sysadmin/helpdesk role into a programmer position, so that is no longer my concern. When it was, however, there was little incentive to use IPv6 - everything worked and continues to work just fine with IPv4, and sometimes there were even some rather esoteric problems with Windows' "Network Location Awareness" when IPv6 was enabled.
When I connect to machines on my home network in any way involving avahi/zeroconf, the machines talk to each other via IPv6 by default.
At work, it's a different story. I have drifted from a sysadmin/helpdesk role into a programmer position, so that is no longer my concern. When it was, however, there was little incentive to use IPv6 - everything worked and continues to work just fine with IPv4, and sometimes there were even some rather esoteric problems with Windows' "Network Location Awareness" when IPv6 was enabled.