I'll add to that - It is still very easy to hijack SMB connections and use it steal the NTLM hash in almost any network with Windows machines (Managed with a DC or not). Just go ahead and try [1] (Disclaimer - running responder.py without authorization might be considered as a crime and I do not take any responsibility for it. I encourage you to use it only if you understand what you are doing and you have full permission to do it).
[1] https://github.com/SpiderLabs/Responder